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( S )- N -(9-(4-(3-(2-((((9 H -fluoren-9-yl)methoxy)carbonyl)amino)-2-carboxyethyl)-1 H -indol-2-yl)phenyl)-6-(dimethylamino)-3 H -xanthen-3-ylidene)- N -methylmeth-anaminium 2,2,2-trifluoroacetate ( 13 ) Iodinated compound 6 (50 mg, 0.10 mmol, 1.0 equiv.), Fmoc-Trp-OH (43 mg, 0.10 mmol, 1.0 equiv.), AgBF 4 (19 mg, 0.10 mmol, 1.0 equiv.) and Pd(OAc) 2 (4.5 mg, 0.02 mmol, 0.2 equiv.) were dissolved in anhydrous DMF (3.0 ml) in a microwave reactor vessel, followed by the addition of trifluoroacetic acid (7.7 μl, 0.10 mmol, 1.0 equiv.)
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